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San Monique is an island in the Carribean, from Live and Let Die. It's ruled by Dr. Kananga as Prime Minister (though he's probably a dictator).
History in the film
The last part of the pre-title sequence of the movie shows the ritualistic murder of MI6 Agent Baines. Highly influenced by voodoo, Baines has blood thrown at him, and is then bitten by a poisonous snake, dying instantly.
James is later sent out there to aid CIA double agent Rosie Carver with investigating Kananga. James easily eliminates a snake sent into his bathroom to kill him (he burns it to death with his cigar and a jet of fire from his deodorant).