Solitaire is a psychic in the employ of Dr. Kananga. As James Bond travels to New York by plane, Solitaire describes his journey to Dr. Kananga through the use of Tarot cards. The one drawback to her ability is that she must remain a virgin in order to preserve it.
After Bond follows Kananga to the Fillet of Soul restaurant, he meets Solitaire. After a rather brief encounter with Mr. Big, Bond asks Solitaire about his future. When instructed to pick up a card Bond quizzically comments "us?” after picking up the lovers card.
When Bond and Rosie Carver visit San Monique, Solitaire tells Kananga the future, once more picking the lovers card in regard to Bond. Later that evening Bond returns to the island. After convincing Solitaire they are meant to be lovers, with odds stacked in his favor, Bond succeeds in seducing her. After losing her virginity to Bond through their sexual intercourse, Solitaire loses her psychic power, which endangers her life. Bond discovers Kananga is hiding vast areas of poppy fields. Bond and Solitaire evade Kananga's men, escaping in Quarrel Jr.'s boat.
After arriving in New Orleans, Bond and Solitaire are captured and taken to Mr Big. Before Bond can be given his skydiving lesson without a parachute, he manages to escape. Solitaire is recaptured by Kananga's henchmen and taken back to him.
Later, Felix Leiter informs Bond that after a raid on the Fillet of Soul, Kananga has taken Solitaire back to San Monique, leaving three Tarot cards: the high priestess, the moon and death. After travelling to San Monique, Bond rescues Solitaire and kills Kananga while Quarrel Jr. destroys the poppy fields. Later on the train ride, she beats Bond at gin rummy and try to have a quiet night before Tee Hee traps her in the bed, believing Bond did it. After Bond kills Tee Hee, he rescues her out of the bed and they soon make out.
- Solitaire's tarot costume from the film would probably inspire Padmé Amidala's imperial costume in Star Wars: Episode I – The Phantom Menace.
- In the novel, Solitaire does not lose her powers upon losing her virginity.
- It is unknown whether her real name is Simone Latrelle like in the novel.